Lavoisier, Antoine-Laurent

▪ French chemist

Introduction

born August 26, 1743, Paris, France

died May 8, 1794, Paris

 prominent French chemist and leading figure in the 18th-century chemical revolution who developed an experimentally based theory of the chemical reactivity of oxygen and coauthored the modern system for naming chemical substances. Having also served as a leading financier and public administrator before the French Revolution, he was executed with other financiers during the revolutionary terror.

Early life and education

      Lavoisier was the first child and only son of a wealthy bourgeois family living in Paris. As a youth he exhibited an unusual studiousness and concern for the public good. After being introduced to the humanities and sciences at the prestigious Collège Mazarin, he studied law. Since the Paris law faculty made few demands on its students, Lavoisier was able to spend much of his three years as a law student attending public and private lectures on chemistry and physics and working under the tutelage of leading naturalists. Upon completing his legal studies, Lavoisier, like his father and his maternal grandfather before him, was admitted to the elite Order of Barristers, whose members presented cases before the High Court ( Parlement) of Paris. But rather than practice law, Lavoisier began pursuing scientific research that in 1768 gained him admission into France's foremost natural philosophy society, the Academy of Sciences (Sciences, Academy of) in Paris.

Pneumatic chemistry

      The chemistry Lavoisier studied as a student was not a subject particularly noted for conceptual clarity or theoretical rigour. Although chemical writings contained considerable information about the substances chemists studied, little agreement existed upon the precise composition of chemical elements or between explanations of changes in composition. Many natural philosophers still viewed the four elements of Greek natural philosophy—earth, air, fire, and water—as the primary substances of all matter. Chemists like Lavoisier focused their attention upon analyzing “mixts” (i.e., compounds), such as the salts formed when acids combine with alkalis. They hoped that by first identifying the properties of simple substances they would then be able to construct theories to explain the properties of compounds.

      It was previously claimed that the elements were distinguishable by certain physical properties: water and earth were incompressible, air could be both expanded and compressed, whereas fire could not be either contained or measured. In the 1720s the English cleric and natural philosopher Stephen Hales (Hales, Stephen) demonstrated that atmospheric air loses its “spring” (i.e., elasticity) once it becomes “fixed” in solids and liquids. Perhaps, Hales suggested, air was really just a vapour like steam, and its spring, rather than being an essential property of the element, was created by heat. Hales's experiments were an important first step in the experimental study of specific airs or gases, a subject that came to be called pneumatic chemistry.

      In the 1750s the Scottish chemist Joseph Black (Black, Joseph) demonstrated experimentally that the air fixed in certain reactions is chemically different from common air. Black wanted to know why slaked quicklime (hydrated calcium oxide) was neutralized when exposed to the atmosphere. He found that it absorbed only one component of the atmosphere, carbon dioxide, which he called “fixed air.” Black's work marked the beginning of investigative efforts devoted to identifying chemically distinct airs, an area of research that grew rapidly during the latter half of the century. Thus, pneumatic chemistry was a lively subject at the time Lavoisier became interested in a particular set of problems that involved air: the linked phenomena of combustion, respiration, and what 18th-century chemists called calcination (the change of metals to a powder [calx], such as that obtained by the rusting of iron).

Conservation of mass (mass, conservation of)

      The assertion that mass is conserved in chemical reactions was an assumption of Enlightenment investigators rather than a discovery revealed by their experiments. Lavoisier believed that matter was neither created nor destroyed in chemical reactions, and in his experiments he sought to demonstrate that this belief was not violated. Still he had difficulty proving that his view was universally valid. His insistence that chemists accepted this assumption as a law was part of his larger program for raising chemistry to the investigative standards and causal explanation found in contemporary experimental physics. While other chemists were also looking for conservation principles capable of explaining chemical reactions, Lavoisier was particularly intent on collecting and weighing all the substances involved in the reactions he studied. His success in the many elaborate experiments he conducted was in large part due to his independent wealth, which enabled him to have expensive apparatus built to his design, and to his ability to recruit and direct talented research associates. The fact that French chemistry students are still taught the conservation of mass as “Lavoisier's law” is indicative of his success in making this principle a foundation of modern chemistry.

Phlogiston theory (phlogiston)

      After being elected a junior member of the Academy of Sciences, Lavoisier began searching for a field of research in which he could distinguish himself. Chemists had long recognized that burning, like breathing, required air, and they also knew that iron rusts only upon exposure to air. Noting that burning gives off light and heat, that warm-blooded animals breathe, and that ores are turned into metals in a furnace, they concluded that fire was the key causal element behind these chemical reactions. The Enlightenment German chemist Georg Ernst Stahl (Stahl, Georg Ernst) provided a well-regarded explanation of these phenomena. Stahl hypothesized that a common “fiery substance” he called phlogiston was released during combustion, respiration, and calcination, and that it was absorbed when these processes were reversed. Although plausible, this theory raised a number of problems for those who wished to explain chemical reactions in terms of substances that could be isolated and measured. In the early stages of his research Lavoisier regarded the phlogiston theory as a useful hypothesis, but he sought ways either to solidify its firm experimental foundation or to replace it with an experimentally sound theory of combustion. In the end his theory of oxygenation replaced the phlogiston hypothesis, but it took Lavoisier many years and considerable help from others to reach this goal.

Marriage and administrative career

      Shortly before entering the Academy of Sciences in 1768, Lavoisier received a considerable inheritance from his mother's estate, which he used to purchase an interest in a financial enterprise known as the General Farm (France). The General Farm was a partnership that had a contract with the royal government to collect certain sales and excise taxes, such as those on salt and tobacco. At the beginning of each financial cycle the Tax Farmers lent money to the government and were subsequently reimbursed through tax collections. Lavoisier spent considerable time as a Tax Farmer, and he was richly rewarded for his efforts. Although chemistry was Lavoisier's passion, throughout his life he devoted the majority of his time to financial and administrative affairs.

      Three years after joining the General Farm, Lavoisier married Marie Anne Paulze, the 14-year-old daughter of a member of the Farm with whom he worked. Although not educated in science, Marie Anne was a spirited and intelligent young woman who created a place for herself in a world of science that provided few opportunities for women. As Marie Anne and Lavoisier had no children, Marie Anne was able to devote her attentions to helping her husband in his research, and she soon became widely regarded as a valuable laboratory assistant and hostess. She mastered English, which Lavoisier never did, and translated chemical works for him. She employed her drawing talent to record the research conducted in the laboratory and to prepare engravings of apparatus for publications. Three years after the wedding a correspondent sent his regards to Lavoisier's “philosophical wife,” and shortly thereafter she was being tutored in chemistry by one of Lavoisier's collaborators. In the laboratory she often recorded results that the experimenters dictated to her, and when Lavoisier announced his new theories she played an active role in campaigning for their acceptance.

      Lavoisier also took on administrative duties within the Academy of Sciences and in other government agencies during the final years of the monarchy and the early years of the French Revolution. From 1775 to 1792 he served as a director of the French Gunpowder Administration and succeeded in making France self-sufficient in this critical military material. He also conducted extensive experiments on agricultural production, advised the government on financial affairs and banking, and served on a commission whose efforts to unify weights and measures led to the adoption of the metric system (metric space). Lavoisier has rightly gained renown for his scientific achievements, but his efforts on behalf of France should also be remembered.

Oxygen theory of combustion

      The oxygen theory of combustion (oxidation–reduction reaction) resulted from a demanding and sustained campaign to construct an experimentally grounded chemical theory of combustion, respiration, and calcination. The theory that emerged was in many respects a mirror image of the phlogiston theory, but gaining evidence to support the new theory involved more than merely demonstrating the errors and inadequacies of the previous theory. From the early 1770s until 1785, when the last important pieces of the theory fell into place, Lavoisier and his collaborators performed a wide range of experiments designed to advance many points on their research frontier.

      Lavoisier's research in the early 1770s focused upon weight gains and losses in calcination. It was known that when metals slowly changed into powders (calxes), as was observed in the rusting of iron, the calx actually weighed more than the original metal, whereas when the calx was “reduced” to a metal, a loss of weight occurred. The phlogiston theory did not account for these weight changes, for fire itself could not be isolated and weighed. Lavoisier hypothesized that it was probably the fixation and release of air, rather than fire, that caused the observed gains and losses in weight. This idea set the course of his research for the next decade.

      Along the way, he encountered related phenomena that had to be explained. Mineral acids, for instance, were made by roasting a mineral such as sulfur in fire and then mixing the resultant calx with water. Lavoisier had initially conjectured that the sulfur combined with air in the fire and that the air was the cause of acidity. However, it was not at all obvious just what kind of air made sulfur acidic. The problem was further complicated by the concurrent discovery of new kinds of airs within the atmosphere. British pneumatic chemists made most of these discoveries, with Joseph Priestley (Priestley, Joseph) leading the effort. And it was Priestley, despite his unrelenting adherence to the phlogiston theory, who ultimately helped Lavoisier unravel the mystery of oxygen. Priestley isolated oxygen in August 1774 after recognizing several properties that distinguished it from atmospheric air. In Paris at the same time, Lavoisier and his colleagues were experimenting with a set of reactions identical to those that Priestley was studying, but they failed to notice the novel properties of the air they collected. Priestley visited Paris later that year and at a dinner held in his honour at the Academy of Sciences informed his French colleagues about the properties of this new air. Lavoisier, who was familiar with Priestley's research and held him in high regard, hurried back to his laboratory, repeated the experiment, and found that it produced precisely the kind of air he needed to complete his theory. He called the gas that was produced oxygen, the generator of acids. Isolating oxygen allowed him to explain both the quantitative and qualitative changes that occurred in combustion, respiration, and calcination.

The chemical revolution

      In the canonical history of chemistry Lavoisier is celebrated as the leader of the 18th-century chemical revolution and consequently one of the founders of modern chemistry. Lavoisier was indeed an indefatigable and skillful investigator; however, his experiments emphasized quantification and demonstration rather than yielding critical discoveries. Such an emphasis suited his determination to elevate chemistry to the level of a rigorous science. Unlike Priestley, he was not a person whom someone of modest self-esteem was likely to find attractive. Wealthy, high-minded, and enormously ambitious, Lavoisier was rationality and purposefulness personified. While his scientific achievements are indisputably of the first rank, his defining achievement was what might be called legislating for science. He led by example as well as precept, and those who worked with him revered him. But many who did not share his vision of chemistry and the chemical revolution he championed found his manner arrogant and his prescriptive claims unpersuasive.

      Lavoisier was fortunate in having made his contributions to the chemical revolution before the disruptions of political revolution. By 1785 his new theory of combustion was gaining support, and the campaign to reconstruct chemistry according to its precepts began. One tactic to enhance the wide acceptance of his new theory was to propose a related method of naming chemical substances. In 1787 Lavoisier and three prominent colleagues published a new nomenclature of chemistry, and it was soon widely accepted, thanks largely to Lavoisier's eminence and the cultural authority of Paris and the Academy of Sciences. Its fundamentals remain the method of chemical nomenclature in use today. Two years later Lavoisier published a programmatic Traité élémentaire de chimie (Elementary Treatise on Chemistry) that described the precise methods chemists should employ when investigating, organizing, and explaining their subjects. It was a worthy culmination of a determined and largely successful program to reinvent chemistry as a modern science.

The French Revolution and Lavoisier's execution

      When the French Revolution began in 1789, Lavoisier, like many other philosophically minded administrators, saw it as an opportunity to rationalize and improve the nation's politics and economy. Such optimism was soon tempered, however, by upheavals that put the very existence of the state at risk. Lavoisier, perhaps overvaluing the authority of science and the power of reason, continued to advise revolutionary governments on finance and other matters, and neither he nor his wife fled abroad when popular anger turned against those who had exercised power and enjoyed social privileges in the old regime. As the revolution became increasingly radical and those in command were driven to ruling by terror, Lavoisier continued to argue that the Academy of Sciences should be saved because its members were loyal and indispensable servants of the state. This rear-guard action was unsuccessful, and he soon found himself imprisoned along with other members of the General Farm. The Republic was being purged of its royalist past. In May 1794 Lavoisier, his father-in-law, and 26 other Tax Farmers were guillotined. Acknowledging Lavoisier's scientific stature, his contemporary, Joseph-Louis Lagrange (Lagrange, Joseph-Louis, comte de l'Empire), commented, “It took them only an instant to cut off that head, and a hundred years may not produce another like it.”

Arthur L. Donovan

Additional Reading

Henry Guerlac, “Antoine-Laurent Lavoisier,” in Dictionary of Scientific Biography, vol. 8 (1973), pp. 66–91, is a fully annotated biographical article of Lavoisier's scientific contributions. For more extensive accounts of Lavoisier's science and life, see Frederic Lawrence Holmes, Lavoisier and the Chemistry of Life: An Exploration of Scientific Creativity (1985); Arthur Donovan, Antoine Lavoisier: Science, Administration, and Revolution (1993, reissued 1996); and Jean-Pierre Poirier, Lavoisier: Chemist, Biologist, Economist (1996, reissued 1998; originally published in French, 1993).A definitive annotated survey of Lavoisier's writing is presented in Denis I. Duveen and Herbert S. Klickstein, A Bibliography of the Works of Antoine Laurent Lavoisier, 1743–1794 (1954), with a Supplement (1965). Antoine Laurent Lavoisier, Oeuvres de Lavoisier, 6 vol. (1862–93, reprinted 1965), is a collected edition that includes all his principal works and memoirs from the academy volumes, as well as numerous miscellaneous writings.Arthur L. Donovan

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