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Introduction of any of various substances between sliding surfaces to reduce wear and friction.

Lubricants may secondarily control corrosion, regulate temperature, electrically insulate, remove contaminants, or damp shock. Prehistoric peoples used mud and reeds to lubricate sledges, timbers, or rocks. Animal fat lubricated the axles of the first wagons and continued in wide use until crude oil became the chief source of lubricants. Crude oil has been the basis of products designed for the specific lubricating needs of automobiles, aircraft, locomotives, turbojets, and all other power machinery. There are three basic varieties of lubrication: fluid-film (in which a fluid film completely separates sliding surfaces), boundary (in which the friction between surfaces is determined by the properties of the surfaces and properties of the lubricant other than viscosity), and solid (used when liquid lubricants lack adequate resistance to load or temperature extremes). The principal lubricants are liquid, oily materials (petroleum-based or synthetic, and including greases); solids (such as graphite, molybdenum disulfide, soft metals, waxes, and plastics); and gases.

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      introduction of any of various substances between sliding surfaces to reduce wear and friction. Nature has been applying lubrication since the evolution of synovial fluid, which lubricates the joints and bursas of vertebrate animals. Prehistoric people used mud and reeds to lubricate sledges for dragging game or timbers and rocks for construction. Animal fat lubricated the axles of the first wagons and continued in wide use until the petroleum industry arose in the 19th century, after which crude oil became the chief source of lubricants. The natural lubricating capacity of crude oil has been steadily improved through the development of a wide variety of products designed for the specific lubricating needs of the automobile, the airplane, the diesel locomotive, the turbojet, and power machinery of every description. The improvements in petroleum lubricants have in turn made possible the increase in speed and capacity of industrial and other machinery.

      There are three basic varieties of lubrication: fluid-film, boundary, and solid.

Fluid-film lubrication.
      Interposing a fluid film that completely separates sliding surfaces results in this type of lubrication. The fluid may be introduced intentionally, as the oil in the main bearings of an automobile, or unintentionally, as in the case of water between a smooth rubber tire and a wet pavement. Although the fluid is usually a liquid, it may also be a gas. The gas most commonly employed is air.

      To keep the parts separated, it is necessary that the pressure within the lubricating film balance the load on the sliding surfaces. If the lubricating film's pressure is supplied by an external source, the system is said to be lubricated hydrostatically. If the pressure between the surfaces is generated as a result of the shape and motion of the surfaces themselves, however, the system is hydrodynamically lubricated. This second type of lubrication depends upon the viscous properties of the lubricant.

Boundary lubrication.
      A condition that lies between unlubricated sliding and fluid-film lubrication is referred to as boundary lubrication, also defined as that condition of lubrication in which the friction between surfaces is determined by the properties of the surfaces and properties of the lubricant other than viscosity. Boundary lubrication encompasses a significant portion of lubrication phenomena and commonly occurs during the starting and stopping of machines.

Solid lubrication.
      Solids such as graphite and molybdenum disulfide are widely used when normal lubricants do not possess sufficient resistance to load or temperature extremes. But lubricants need not take only such familiar forms as fats, powders, and gases; even some metals commonly serve as sliding surfaces in some sophisticated machines.

      A lubricant primarily controls friction and wear, but it can and ordinarily does perform numerous other functions, which vary with the application and usually are interrelated.

Control functions.
       Characteristics of three typical lubricantsThe amount and character of the lubricant made available to sliding surfaces have a profound effect upon the friction that is encountered. For example, disregarding such related factors as heat and wear but considering friction alone between two oil-film lubricated surfaces, the friction can be 200 times less than that between the same surfaces with no lubricant. Under fluid-film conditions, friction is directly proportional to the viscosity of the fluid (see Table 1 (Characteristics of three typical lubricants)). Some lubricants, such as petroleum derivatives, are available in a great range of viscosities and thus can satisfy a broad spectrum of functional requirements. Under boundary lubrication conditions, the effect of viscosity on friction becomes less significant than the chemical nature of the lubricant. Delicate instruments, for example, must not be lubricated with fluids that would attack and corrode the finer metals.

      Wear occurs on lubricated surfaces by abrasion, corrosion, and solid-to-solid contact. Proper lubricants will help combat each type. They reduce abrasive and solid-to-solid contact wear by providing a film that increases the distance between the sliding surfaces, thereby lessening the damage by abrasive contaminants and surface asperities. The role of a lubricant in controlling corrosion of surfaces is twofold. When machinery is idle, the lubricant acts as a preservative. When machinery is in use, the lubricant controls corrosion by coating lubricated parts with a protective film that may contain additives to neutralize corrosive materials. The ability of a lubricant to control corrosion is directly related to the thickness of the lubricant film remaining on the metal surfaces and the chemical composition of the lubricant.

      Lubricants also can assist in controlling temperature by reducing friction and carrying off the heat that is generated. Effectiveness depends upon the amount of lubricant supplied, the ambient temperature, and the provision for external cooling. To a lesser extent, the type of lubricant also affects surface temperature.

Other functions.
      Various lubricants are employed as hydraulic fluids in fluid transmission devices. Others can be used to remove contaminants in mechanical systems. Detergent-dispersant additives, for instance, suspend sludges and remove them from the sliding surfaces of internal-combustion engines.

      In specialized applications such as transformers and switchgear, lubricants with high dielectric constants act as electrical insulators (insulator). For maximum insulating properties, a lubricant must be kept free of contaminants and water. Lubricants also act as shock-damping fluids in energy-transferring devices (e.g., shock absorbers) and around such machine parts as gears that are subjected to high intermittent loads.

      A wide variety of lubricants are available. The principal types are reviewed here.

Liquid, oily lubricants.
      Animal and vegetable products were certainly man's first lubricants and were used in large quantities. But, because they lack chemical inertness and because lubrication requirements have become more demanding, they have been largely superseded by petroleum products and by synthetic materials. Some organic substances such as lard oil and sperm oil are still in use as additives because of their special lubricating properties.

       petroleum lubricants are predominantly hydrocarbon products extracted from fluids that occur naturally within the Earth. They are used widely as lubricants because they possess a combination of the following desirable properties: (1) availability in suitable viscosities, (2) low volatility, (3) inertness (resistance to deterioration of the lubricant), (4) corrosion protection (resistance to deterioration of the sliding surfaces), and (5) low cost.

       Synthetic lubricants and typical applicationsSynthetic lubricants generally can be characterized as oily, neutral liquid materials not usually obtained directly from petroleum but having some properties similar to petroleum lubricants. In certain ways they are superior to hydrocarbon products. Synthetics exhibit greater stability of viscosity with temperature changes, resistance to scuffing and oxidation, and fire resistance. Since the properties of synthetics vary considerably, each synthetic lubricant tends to find a special application. A few of the more common classes of synthetics and typical uses of each are shown in Table 2 (Synthetic lubricants and typical applications).

      Another form of oily lubricant is grease, a solid or semisolid substance consisting of a thickening agent in a liquid lubricant. Soaps of aluminum, barium, calcium, lithium, sodium, and strontium are the major thickening agents. Nonsoap thickeners consist of such inorganic compounds as modified clays or fine silicas, or such organic materials as arylureas or phthalocyanine pigments. Lubrication by grease may prove more desirable than lubrication by oil under conditions when (1) less frequent lubricant application is necessary, (2) grease acts as a seal against loss of lubricant and ingress of contaminants, (3) less dripping or splattering of lubricant is called for, or (4) less sensitivity to inaccuracies in the mating parts is needed.

Solid lubricants.
      A solid lubricant is a film of solid material composed of inorganic or organic compounds or of metal.

      There are three general kinds of inorganic compounds that serve as solid lubricants:

      1. Layer-lattice solids: materials such as graphite and molybdenum disulfide, commonly called molysulfide, have a crystal lattice structure arranged in layers. Strong bonds between atoms within a layer and relatively weak bonds between atoms of different layers allow the lamina to slide on one another. Other such materials are tungsten disulfide, mica, boron nitride, borax, silver sulfate, cadmium iodide, and lead iodide. Graphite's low friction is due largely to adsorbed films; in the absence of water vapour, graphite loses its lubricating properties and becomes abrasive. Both graphite and molysulfide are chemically inert and have high thermal stability.

      2. Miscellaneous soft solids: a variety of inorganic solids such as white lead, lime, talc, bentonite, silver iodide, and lead monoxide are used as lubricants.

      3. Chemical conversion coatings: many inorganic compounds can be formed on a metallic surface by chemical reaction. The best known such lubricating coatings are sulfide, chloride, oxide, phosphate, and oxalate films.

      Solid organic lubricants are usually divided into two broad classes:

      1. Soaps (soap and detergent), waxes (wax), and fats: (fat) this class includes metallic soaps of calcium, sodium, lithium; animal waxes (e.g., beeswax and spermaceti wax); fatty acids (e.g., stearic and palmitic acids); and fatty esters (e.g., lard and tallow).

      2. Polymeric films: these are synthetic substances such as polytetrafluoroethylene and polychlorofluoroethylene. One major advantage of such film-type lubricants is their resistance to deterioration during exposure to the elements. Thus, 1/2-inch- (1.3-centimetre-) thick plates of polymeric film are used in modern prestressed concrete construction to permit thermal movement of beams resting atop columns. Such expansion and contraction of the structural members is facilitated by the long-lived polymeric film plate.

      Thin films of soft metal on a hard substrate can act as effective lubricants, if the adhesion to the substrate is good. Such metals include lead, tin, and indium.

Gaseous lubricants.
       Characteristics of three typical lubricantsLubrication with a gas is analogous in many respects to lubrication with a liquid, since the same principles of fluid-film lubrication apply. Although both gases and liquids are viscous fluids, they differ in two important particulars. The viscosity of gases is much lower and the compressibility much greater than for liquids. Film thicknesses and load capacities therefore are much lower with a gas such as air (see Table 1 (Characteristics of three typical lubricants)). In equipment that handles gases of various kinds, it is often desirable to lubricate the sliding surfaces with gas in order to simplify the apparatus and reduce contamination to and from the lubricant. The list of gases used in this manner is extensive and includes air, steam, industrial gases, and liquid-metal vapours.

      With so many types of materials capable of acting as lubricants under certain conditions, coverage of the properties of all of them is impractical. Mention is made only of those properties usually considered characteristic of commercially significant fluid lubricants.

      Of all the properties of fluid lubricants, viscosity is the most important, since it determines the amount of friction that will be encountered between sliding surfaces and whether a thick enough film can be built up to avoid wear from solid-to-solid contact. Viscosity customarily is measured by a viscometer, which determines the flow rate of the lubricant under standard conditions; the higher the flow rate, the lower the viscosity. The rate is expressed in centipoises, reyns, or seconds Saybolt universal (SSU) depending, respectively, upon whether metric, English, or commercial units are used. In most liquids, viscosity drops appreciably as the temperature is raised. Since little change of viscosity with fluctuations in temperature is desirable to keep variations in friction at a minimum, fluids often are rated in terms of viscosity index. The less the viscosity is changed by temperature, the higher the viscosity index.

Pour point.
      The pour point, or the temperature at which a lubricant ceases to flow, is important in appraising flow properties at low temperature. As such, it can become the determining factor in selecting one lubricant from among a group with otherwise identical properties.

      The flash point, or the temperature at which a lubricant momentarily flashes in the pressure of a test flame, aids in evaluating fire-resistance properties. Like the pour-point factor, the flash point may in some instances become the major consideration in selecting the proper lubricant, especially in lubricating machinery handling highly flammable material.

      Oiliness generally connotes relative ability to operate under boundary lubrication conditions. The term relates to a lubricant's tendency to wet and adhere to a surface. There is no formal test for the measurement of oiliness; determination of this factor is chiefly through subjective judgment and experience. The most desirable lubricant for a specific use need not necessarily be the oiliest; e.g., long-fibre grease, which is low in oiliness as compared with machine oils, is usually preferable for packing rolling bearings.

Neutralization number.
      The neutralization number is a measure of the acid or alkaline content of new oils and an indicator of the degree of oxidation degradation of used oils. This value is ascertained by titration, a standard analytical chemical technique, and is defined as the number of milligrams of potassium hydroxide required to neutralize one gram of the lubricant.

Penetration number.
      The penetration number, applied to grease, is a measure of the film characteristics of the grease. The test consists of dropping a standard cone into the sample of grease being tested. Gradations indicate the depth of penetration: the higher the number, the more fluid the grease.

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Universalium. 2010.

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