spinel

/spi nel", spin"l/, n.

1. any of a group of minerals composed principally of oxides of magnesium, aluminum, iron, manganese, chromium, etc., characterized by their hardness and octahedral crystals.

2. a mineral of this group, essentially magnesium aluminate, MgAl₂O₄, some varieties being used as gems.

Also, spinelle.

[1520-30; < F spinelle < It spinella, equiv. to spin(a) thorn ( < L spina) + -ella -ELLE]

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Mineral composed of magnesium aluminum oxide (MgAl₂O₄).

Also called magnesia spinel, its colour, due to various impurities, ranges from blood-red to blue, green, brown, and colourless. Spinel is found in basic igneous rocks, granite pegmatites, and contact metamorphic limestone deposits, often in association with corundum. Synthetic spinel has been manufactured since the early 20th century for use as imitation gem stones. Spinel may also refer more broadly to any of various mineral oxides of magnesium, iron, zinc, or manganese in combination with aluminum, chromium, or iron.

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▪ mineral

      mineral composed of magnesium aluminum oxide (MgAl₂O₄) or any member of a group of rock-forming minerals, all of which are metal oxides with the general composition AB₂O₄, in which A may be magnesium, iron, zinc, manganese, or nickel; B may be aluminum, chromium, or iron; and O is oxygen. The spinel group is divided into three immiscible series: the spinel (aluminum-spinel) series, in which B is aluminum; the chromite (chromium-spinel) series, in which B is chromium; and the magnetite (iron-spinel) series, in which B is iron.

      The aluminum spinels are harder, more transparent, and less dense than the others. The spinel series contains the mineral spinel, also called ruby spinel (q.v.) or magnesia spinel; other members include hercynite (iron aluminum oxide, FeAl₂O₄), gahnite (zinc aluminum oxide, ZnAl₂O₄), and galaxite (manganese aluminum oxide, MnAl₂O₄). The colour of magnesia spinel ranges from bloodred to blue, green, brown, and colourless; gahnite is dark blue-green; hercynite and galaxite are black. These minerals are found as glassy, hard octahedrons, grains or masses in basic igneous rocks, granite pegmatites, and contact metamorphic limestone deposits. The members of the spinel series often substitute for one another in the crystal structure, so that most specimens are mixtures.

      For general information on the use and occurrence of the chromium- and iron-spinel series, see chromite; magnetite. For detailed physical properties of any of the spinel minerals, see oxide mineral (table). More than 200 synthetic varieties of spinels have been prepared, several as gemstones and many as ferrimagnetic materials (see also ferrite).

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