scandium

/skan"dee euhm/, n. Chem.

a rare, trivalent, metallic element obtained from thortveitite. Symbol: Sc; at. wt.: 44.956; at. no.: 21; sp. gr.: 3.0.

[1875-80; < NL; see SCANDIA, -IUM]

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▪ chemical element

 (Sc), chemical element, rare-earth metal of transition Group IIIb of the periodic table. Scandium is a silvery-white, rather soft metal. After Dmitry Ivanovich Mendeleyev predicted (1871) its existence, tentatively calling it ekaboron, Lars Fredrik Nilson discovered (1879) its oxide, scandia, in the rare-earth minerals gadolinite and euxenite, and Per Teodor Cleve (Cleve, Per Teodor) (later in 1879) identified scandium with the hypothetical ekaboron.

      Scandium is found in small proportions in many of the heavy rare-earth ores of Scandinavia and elsewhere and in many tin and tungsten ores; it also occurs in the products of nuclear fission. The cosmic abundance of scandium is relatively high. Although it is only about the 50th most abundant element on Earth, it is about the 23rd most abundant element in the Sun.

      Scandium is easily separated from the other rare earths by precipitation of the very insoluble potassium scandium sulfate or by extraction of scandium thiocyanate by diethyl ether. The metal itself was first prepared (1938) by the electrolysis of potassium, lithium, and scandium chlorides in a eutectic mixture (i.e., a mixture having the lowest melting point possible with those components). Scandium is now produced on a small scale mostly as a by-product of uranium extraction from the mineral davidite, which contains about 0.02 percent scandium oxide. Very few uses of this unusual metal have been developed. Its low density and high melting point suggest applications as an alloying agent for devices requiring lightweight metals. After irradiation in an atomic pile, scandium emits strong gamma radiation with an 85-day half-life, for which it could be used in radiotherapy.

      The chemistry of scandium bears a closer resemblance to that of the other rare-earth elements of oxidation state +3 than to that of aluminum or titanium. Some of its behaviour, however, is atypical of the rare earths because of its significantly smaller ionic radius (0.73 angstrom [Å]) as compared with the rare-earth average (0.96 Å). For this reason the Sc³⁺ ion is a relatively strong acid and has a much greater tendency to form complex ions. The Sc³⁺ ion is paramagnetic. Natural scandium is wholly composed of the stable isotope scandium-45.

atomic number

21

atomic weight

44.956

melting point

1,539° C

boiling point

2,832° C

specific gravity

2.989 (25° C)

oxidation state

+3

electronic config.

[Ar]3d¹4s²

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