mean free path

Physics, Chem. (in a collection of moving particles)the average distance that a particle travels between successive collisions with other particles.

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▪ physics

      average distance an object will move between collisions. The actual distance a particle, such as a molecule in a gas, will move before a collision, called free path, cannot generally be given because its calculation would require knowledge of the path of every particle in the region. The probability (dP) that a molecule will move a distance between two points (x and x + dx) without collision is proportional to an exponential factor; that is, dP = e^-x/μdx, in which e is the base of natural logarithms. The constant μ is the mean free path and is the average (mean) distance traveled by a molecule between collisions. The mean free path of an oxygen gas molecule under a pressure of 1 atmosphere at 0° C is about 6 × 10^-6 cm (2 × 10⁻⁶ inch).

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